If the lids were open, there would be dead air space in which to allow the accumulation of fumes.
The backs are in a position where there is no air circulating. Top of the guitar has an air space between the top and inside of the lid.
Ummm, huh?
If the lids were open, normal room air currents would NOT allow for a 'dead air space in which to allow the accumulation of fumes.' Just the opposite, hence my mentioning it. In such a case, if the problem was due to outgassing, the sides and back would be the areas affected with the tops and neck protected by circulating air.
If the lid is closed, there is also are space around the neck, finished with the same materials. The problem should be as prevalent on necks as on the tops if your theory is correct.
Outgassing takes place over years, not days or weeks. There may be as yet, undocumented reactions between the adhesive and the various materials in the case and guitar. The reaction that I suspect may be taking place requires the fumes, plus oxygen. There may also be other factors involved. I'm starting with the ones that are most obvious to me.
The glues used on PRS cases are water based. The high volatility means that once the glues are dried on PRS' drying racks in their highly humidity controlled factory, there is no more moisture outgassing.
That doesn't mean there couldn't be outgassing from the fabrics or other case materials which have lower volitivity. But if that were the case (unintentional pun), we'd see this all over the world with all older PRS guitars that spend lots of time in their cases, like, for example, mine. And we don't.
Because the problem is little reported, I suspect it is a local storage/humidity/care/handling problem with your friend.
I've seen guitars which have been poorly stored in excessively humid conditions. These don't look like that problem, as I've seen it in the past.
Delamination, as I know it, usually involves the finish becoming detached from the substrate. I have not seen any areas of the finish actually lifting or bubbling.
Delamination starts microscopically. Air and moisture infiltration produce the haze. No visible lifting or bubbling need be evident.
If the condition was due to improper storage, I would expect to see it on many of the other guitars in the collection. It's present exclusively on the PRS guitars.
Other brands which use similar finish (ie, not nitro lacquer) have not been similarly affected.
Lots of things can account for this. Are the PRS guitars played more? Are guitars always wiped down after playing? Are guitars left out or even just stored in poorly controlled humidity?
Know also that PRS finishes are among the thinnest in the industry, designed that way to enhance tone. Fine finishes require much more attention to care than the relatively thick finishes on other guitars.
Please don't misconstrue this as an attack on PRS. I hold these instruments in the highest regard, and have joined this forum to communicate with like-minded individuals who may have encountered this problem.
I sincerely appreciate you taking the time to reply. I was unaware that the factory actually seasoned the cases after assembly.
Cases are manufactured for PRS by an outside case company to PRS specifications. When PRS gets a shipment of clases in, they are unpacked, opened and set on drying racks in the tightly temperature and humidity controlled factory. I don't know how long they are dried, just that they ensure that every drop of moisture is out and that the glues are fully cured.
PRS is an exceedingly detail focused company. Things like humidity and the moisture content of their materials are smack dab in the middle or their radar screen.